主题式复习讲座6——《治疗疟疾的药物——磷酸氯喹》: 115619tj1v4j52nrrxen87.png

<div class="wx_rich_media_content" id="jsWxContainer"><section style="text-align: center;" nodeleaf=""><span class="wxart_image" wx-style="display:inline-block;height: auto !important;"></span></section><p data-pm-slice="0 0 []"><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">氯喹可以治疗</span></span></span><span style="font-family: 宋体; color: rgb(51, 51, 51); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">疟疾，但</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">临床试验发现，氯喹的水溶性较弱，单独服用往往药效不佳。目前市面上商品化的氯喹药物</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">——</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">磷酸氯喹，是利用磷酸与氯喹形成有机盐，增大其在水中的溶解度，从而提高了氯喹的药效。</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><o:p></o:p></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><br></span></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">1</span></span></span><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．磷酸氯喹的结构简式为：</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">  </span></span><o:p></o:p></span></p><section nodeleaf=""><span class="wxart_image" wx-style="display:inline-block;width: 261px;height: auto !important;"></span></section><p><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">（</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">1</span></span></span><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">）</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">磷酸与氯喹形成了有机盐，则磷酸氯喹中含有的化学键</span></span></span><u><span style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span></span></u><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">。（不定项）</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><o:p></o:p></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">A</span></span></span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．离子键</span></span></span><span style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span lang="EN-US"><span leaf=""><span textstyle="" style="font-size: 16px;">     </span></span><span leaf=""><span textstyle="" style="font-size: 16px;">B</span></span></span></span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．共价键</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><o:p></o:p></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">C</span></span></span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．金</span></span><span style="color:#1C1F23;"><span leaf=""><span textstyle="" style="font-size: 16px;">属键</span></span></span></span><span style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span lang="EN-US"><span leaf=""><span textstyle="" style="font-size: 16px;">     </span></span><span leaf=""><span textstyle="" style="font-size: 16px;">D</span></span></span></span><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．氢键</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><o:p></o:p></span></p><p><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><br></span></span></p><p><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">（</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">2</span></span></span><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">）</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">磷酸氯喹中有含有</span></span></span><u><span style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span lang="EN-US"><span leaf=""><span textstyle="" style="font-size: 16px;">  </span></span></span></span></u><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">个不对称碳原子，</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">N</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">原子的杂化方式有</span></span></span><u><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">   </span></span></span></u><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">。</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><o:p></o:p></span></p><p><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><br></span></span></p><p><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">（</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">3</span></span></span><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">）</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">PO</span></span>_{<span leaf=""><span textstyle="" style="font-size: 16px;">4</span></span>}^{<span leaf=""><span textstyle="" style="font-size: 16px;">3</span></span>}</span>^{<span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">−</span></span></span>}<span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">的空间构型为</span></span></span><u><span style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span lang="EN-US"><span leaf=""><span textstyle="" style="font-size: 16px;">  </span></span><span leaf=""><span textstyle="" style="font-size: 16px;">     </span></span></span></span></u><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">。</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><o:p></o:p></span></p><p><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><br></span></span></p><p><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">（</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">4</span></span></span><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">）</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">磷酸氯喹中苯环上二溴取代物种类</span></span></span><u><span style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span lang="EN-US"><span leaf=""><span textstyle="" style="font-size: 16px;">  </span></span></span></span></u><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">（填</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">“</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">＞</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">”“</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">＜</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">”“=”</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">）一溴取代物种类。</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><o:p></o:p></span></p><p><span style="font-family: 宋体; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><br></span></span></p><p><span style="font-family: 宋体; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">答案：（</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">1</span></span></span><span style="font-family: 宋体; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">）</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">AB</span></span><o:p></o:p></span></p><p><span style="font-family: 宋体; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">（</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">2</span></span></span><span style="font-family: 宋体; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">）</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">1</span></span><span leaf=""><span textstyle="" style="font-size: 16px;">  </span></span><span leaf=""><span textstyle="" style="font-size: 16px;">sp</span></span>^{<span leaf=""><span textstyle="" style="font-size: 16px;">3</span></span>}<span leaf=""><span textstyle="" style="font-size: 16px;">  </span></span><span leaf=""><span textstyle="" style="font-size: 16px;">sp</span></span>^{<span leaf=""><span textstyle="" style="font-size: 16px;">2</span></span>}<o:p></o:p></span></p><p><span style="font-family: 宋体; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">（</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">3</span></span></span><span style="font-family: 宋体; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">）正四面体</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><o:p></o:p></span></p><p><span style="font-family: 宋体; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">（</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">4</span></span></span><span style="font-family: 宋体; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">）</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">=</span></span><o:p></o:p></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><br></span></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">2</span></span></span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．氯喹与磷酸反应生成磷酸氯喹，其主要目的是</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">___</span></span></span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">。</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">  </span></span><o:p></o:p></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">A</span></span></span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．增强水溶性</span></span></span><span style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span lang="EN-US"><span leaf=""><span textstyle="" style="font-size: 16px;">    </span></span><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><o:p></o:p></span></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">B</span></span></span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．提高热稳定性</span></span></span><span style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span lang="EN-US"><span leaf=""><span textstyle="" style="font-size: 16px;">  </span></span><span style="color:#1C1F23;"><span leaf=""><span textstyle="" style="font-size: 16px;">  </span></span><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><o:p></o:p></span></span></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">C</span></span></span><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．增加脂溶性</span></span></span><span style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span lang="EN-US"><span leaf=""><span textstyle="" style="font-size: 16px;">    </span></span><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><o:p></o:p></span></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">D</span></span></span><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．降低毒性</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><o:p></o:p></span></p><p><span style="font-family: 宋体; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><br></span></span></p><p><span style="font-family: 宋体; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">答案：</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">A</span></span><o:p></o:p></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><br></span></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">3</span></span></span><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．根据磷酸氯喹的结构，回答：</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><o:p></o:p></span></p><p><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">（</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">1</span></span></span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">）</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">1 mol</span></span></span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">磷酸氯喹最多可与</span></span></span><u><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">  </span></span></span></u><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span leaf=""><span textstyle="" style="font-size: 16px;">mol H</span></span>_{<span leaf=""><span textstyle="" style="font-size: 16px;">2</span></span>}</span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">发生加成反应，最多消耗</span></span></span><u><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">  </span></span></span></u><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span leaf=""><span textstyle="" style="font-size: 16px;">mol NaOH</span></span></span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">。</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><o:p></o:p></span></p><p><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><br></span></span></p><p><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">（</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">2</span></span></span><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">）磷酸氯喹不能发生的反应有</span></span></span><u><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">   </span></span></span></u><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">。</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><o:p></o:p></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">A</span></span></span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．加成反应</span></span></span><span style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span lang="EN-US"><span leaf=""><span textstyle="" style="font-size: 16px;">   </span></span><span leaf=""><span textstyle="" style="font-size: 16px;">B</span></span></span></span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．取代反应</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><o:p></o:p></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">C</span></span></span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．氧化反应</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">  </span></span><span leaf=""><span textstyle="" style="font-size: 16px;">  </span></span><span leaf=""><span textstyle="" style="font-size: 16px;">D</span></span></span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．加聚反应</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><o:p></o:p></span></p><p><span style="font-family: 宋体; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><br></span></span></p><p><span style="font-family: 宋体; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">答案：（</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">1</span></span></span><span style="font-family: 宋体; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">）</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">5 </span></span><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span leaf=""><span textstyle="" style="font-size: 16px;">8 </span></span><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span></span><span style="font-family: 宋体; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">（</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">2</span></span></span><span style="font-family: 宋体; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">）</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: red; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">D</span></span><o:p></o:p></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><br></span></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">4</span></span></span><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．把下面的仪器分析法与主要功能连接起来：</span></span></span></p><section nodeleaf=""><span class="wxart_image" wx-style="display:inline-block;width: 578px;height: auto !important;"></span></section><p><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><br></span></span></p><p><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">5</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">．</span></span></span><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">合成磷酸氯喹的主要原料是氯喹，结构简式如下：</span></span></span><span style="font-family: &quot;Times New Roman&quot;, serif;"><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span></span></p><section nodeleaf=""><span class="wxart_image" wx-style="display:inline-block;width: 514px;height: auto !important;"></span></section><p><span style="font-family: &quot;Times New Roman&quot;, serif;"><span leaf=""><span textstyle="" style="font-size: 16px;">（</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">1</span></span></span><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">）</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">信息</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">i</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">的反应类型是</span></span></span><u><span style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span lang="EN-US"><span leaf=""><span textstyle="" style="font-size: 16px;">  </span></span></span></span></u><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">。</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><o:p></o:p></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">A</span></span></span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．加成反应</span></span></span><span style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span lang="EN-US"><span leaf=""><span textstyle="" style="font-size: 16px;">  </span></span><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span leaf=""><span textstyle="" style="font-size: 16px;">B</span></span></span></span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．取代反应</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><o:p></o:p></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">C</span></span></span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．消去反应</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">  </span></span><span leaf=""><span textstyle="" style="font-size: 16px;">  </span></span><span leaf=""><span textstyle="" style="font-size: 16px;">D</span></span></span><span style="font-family: 宋体; background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">．加成反应</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;"><o:p></o:p></span></p><p><span style="font-family: 宋体;color: black;"><span leaf=""><br></span></span></p><p><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">（</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">2</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">）信息</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">ii</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">的另一生成物是</span></span></span><u><span style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span lang="EN-US"><span leaf=""><span textstyle="" style="font-size: 16px;">   </span></span></span></span></u><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">。</span></span></span></p><p><span style="font-family: 宋体;color: black;"><span leaf=""><br></span></span></p><section nodeleaf=""><span class="wxart_image" wx-style="display:inline-block;width: 298px;height: auto !important;"></span></section><p><span style="font-family: 宋体;color: black;"><span leaf=""><br></span></span></p><p><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;color: rgb(255, 0, 0);">答案：（</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: red;"><span leaf=""><span textstyle="" style="font-size: 16px;">1</span></span></span><span style="font-family: 宋体;color: red;"><span leaf=""><span textstyle="" style="font-size: 16px;">）</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: red;"><span leaf=""><span textstyle="" style="font-size: 16px;">B </span></span><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span></span><span style="font-family: 宋体;color: red;"><span leaf=""><span textstyle="" style="font-size: 16px;">（</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: red;"><span leaf=""><span textstyle="" style="font-size: 16px;">2</span></span></span><span style="font-family: 宋体;color: red;"><span leaf=""><span textstyle="" style="font-size: 16px;">）</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: red;"><span leaf=""><span textstyle="" style="font-size: 16px;">HX</span></span><o:p></o:p></span></p><p style="margin-right: 117pt; margin-left: 1pt; text-align: justify;"><span style="font-family: 宋体;color: red;"><span leaf=""><span textstyle="" style="font-size: 16px;">（</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: red;"><span leaf=""><span textstyle="" style="font-size: 16px;">3</span></span></span><span style="font-family: 宋体;color: red;"><span leaf=""><span textstyle="" style="font-size: 16px;">）略（直接套用信息即可）</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: red;"><o:p></o:p></span></p><p style="margin-right: 117pt; margin-left: 1pt; text-align: justify;"><span style="font-family: 宋体;color: red;"><span leaf=""><span textstyle="" style="font-size: 16px;"><br></span></span></span></p><section nodeleaf=""><span class="wxart_image" wx-style="display:inline-block;width: 493px;height: auto !important;"></span></section><p><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">间氯硝基苯的熔点为</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">44</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">～</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">46℃</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">，沸点为</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">235</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">～</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">236℃</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">。下列说法正确的是</span></span></span><u><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span><span leaf=""><span textstyle="" style="font-size: 16px;"> </span></span></span></u><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">。</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><o:p></o:p></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">A</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">．间氯硝基苯与硝基苯互为同系物</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><o:p></o:p></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">B</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">．间氯硝基苯常温下呈液态，不溶于水，易溶于苯和甲苯</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><o:p></o:p></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;"><span leaf=""><span textstyle="" style="font-size: 16px;">C</span></span></span><span style="font-family: 宋体;"><span leaf=""><span textstyle="" style="font-size: 16px;">．由间氯硝基苯制备间氯苯胺，该过程发生了还原反应</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;"><o:p></o:p></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">D</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">．间氯苯胺分子内含有三个碳碳双键</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;"><o:p></o:p></span></p><p style="margin-left: 1.15pt;"><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><br></span></span></p><p style="margin-left: 1.15pt;"><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">（</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">2</span></span></span><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">）写出符合下列条件的</span></span></span><span style="font-family: 宋体;color: black;"><span leaf=""><span textstyle="" style="font-size: 16px;">间氯苯胺的同系物的结构简式：</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;color: black;"><o:p></o:p></span></p><p><span style="font-family: 宋体;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">①</span></span></span><span style="font-family: 宋体;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">质谱图中分子离子峰的</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">m/z</span></span></span><span style="font-family: 宋体;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">值为</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">84</span></span></span><span style="font-family: 宋体;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">；</span></span></span><span style="font-family: &quot;Times New Roman&quot;, serif;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);"> </span></span><span lang="EN-US"><o:p></o:p></span></span></p><p><span style="font-family: 宋体;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">②</span></span></span><span style="font-family: 宋体;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">核磁共振氢谱显示分子中存在三类化学环境不同的氢原子，其数量之比为</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">3</span></span></span><span style="font-family: 宋体;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">∶</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">1</span></span></span><span style="font-family: 宋体;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">∶</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">1</span></span></span><span style="font-family: 宋体;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">。</span></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif;"><o:p></o:p></span></p><p><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">____________</span></span></span><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">。</span></span></span></p><p data-pm-slice="0 0 []"><span leaf=""><br></span></p><p data-pm-slice="0 0 []"><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">（</span></span><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">3</span></span><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">）已知：① </span></span><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">−Cl </span></span><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">是苯环的</span></span><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">“</span></span><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">邻对位</span></span><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">”</span></span><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">定位基团，</span></span><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">−NO</span></span><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">2 </span></span><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">是苯环的</span></span><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">“</span></span><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">间位</span></span><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">”</span></span><span leaf=""><span textstyle="" style="font-size: 16px; color: rgb(0, 0, 0);">定位基团；</span></span></p><p><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><br></span></span></p><section nodeleaf=""><span class="wxart_image" wx-style="display:inline-block;width: 452px;height: auto !important;"></span></section><section nodeleaf=""><span class="wxart_image" wx-style="display:inline-block;width: 578px;height: auto !important;"></span></section><p><span style="font-family: 宋体; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><br></span></span><span lang="EN-US" style="font-family: &quot;Times New Roman&quot;, serif; color: rgb(28, 31, 35); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><o:p></o:p></span></p><section><span style="font-size: 10.5pt; font-family: 宋体; color: rgb(0, 112, 192); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">《范汝广说化学》：</span></span></span><span lang="EN-US" style="font-size: 10.5pt; font-family: &quot;Times New Roman&quot;, serif; color: rgb(0, 112, 192); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">18101846096</span></span></span><span style="font-size: 10.5pt; font-family: 宋体; color: rgb(0, 112, 192); background-image: initial; background-position: initial; background-size: initial; background-repeat: initial; background-attachment: initial; background-origin: initial; background-clip: initial;"><span leaf=""><span textstyle="" style="font-size: 16px;">（微信同号）</span></span></span></section><p style="display: none;"><mp-style-type data-value="3"></mp-style-type></p></div><p></p>